Foaming supramolecular surfactants for gas mobility control in naturally fractured carbonate reservoirs at high temperature,salinity,and hardness  

作　　者：Enrique Soto-Castruita Raúl Hern andez-Altamirano Eduardo Buenrostro-González Erick-Emanuel Luna-Rojero Sung Jae Ko-Kim Violeta-Yasmín Mena-Cervantes Mirna Pons-Jiménez Jorge-Francisco Ramírez-Pérez David-Aaσn Nieto-Alvarez Ricardo Cerón-Camacho Jos e-Ernesto Parra Raúl Oviedo-Roa Jos e-Manuel Martínez-Magadán Rodolfo Cisneros-Dévora Luis-S.Zamudio-Rivera 

机构地区：[1]Instituto Mexicano del Petr oleo,Eje Central Lazaro Cardenas Norte 152,Col.San Bartolo Atepehuacan,Ciudad de Mexico,07730,Mexico [2]CONACy T-Instituto Mexicano del Petroleo,Eje Central Lazaro Cardenas Norte 152,Col.San Bartolo Atepehuacan,Ciudad de Mexico,07730,Mexico [3]Centro Mexicano para la Produccion mas Limpia,Instituto Politecnico Nacional,Avenida Acueducto s/n,Col.La Laguna Ticoman,Ciudad de Mexico,07340,Mexico [4]Centro de Tecnologías para Exploracion y Produccion,Camino de Terracería 800,Col.San Jose Novillero,Boca delRío,Veracruz,94286,Mexico

出　　处：《Petroleum Science》2022年第6期3134-3148,共15页石油科学（英文版）

基　　金：supports granted by Instituto Mexicano del Petr oleo (IMP) through the Project Y.00123 “Procesos de RM en yacimientos carbonatados fracturados de alta salinidad y temperatura con base en el dise~no, desarrollo y escalamiento de productos químicos ad hoc”;financially supported by the SENER-CONACYT/Hidrocarburos fund through the Project 146735, D.61029 “Dise~no y síntesis de nuevos prototipos de productos químicos multifuncionales con propiedades dispersantes de asfaltenos modificadoras de la mojabilidad y desemulsificantes”

摘　　要：Oil production and mainte nance are essential issues in naturally fractured reservoirs because they are the largest and most productive on earth.However,they present early water and gas channeling but could be remediated by using foaming agents to control these phenomena through blocking channeling areas.In Mexico these reservoirs have pressure up to 5,500 psi,high temperature up to 200℃,salinity up to400,000 ppm,and hardness up to 250,000 ppm;due to these thermodynamic conditions,there has been no available technology to form stable enough foams.In this work,a foaming supramolecular surfactant with the capability to chelate Ca^(2+)ions is examined.As a result,surfactant monomers are bridged by captured Ca^(2+)cations leading to the formation of high-molecular-weight oligomers,which significantly increment the viscosity of the solution improving the foam stability,and since at this manner the Ca2+cations are no longer available to precipitate as components of solid salts,the foaming supramolecular surfactant also performs as antiscalant.These observations are explained through quantum theoretical modeling.The foam is stable,effectively blocking the gas channels,whereas in presence of oil the foam is broken leading the oil to pass into the wellbore.The characteristic rheological properties of the foam allow its injection into the formation at a range of flow rates,foam qualities,and shear stress to achieve the flooding and the blocking of a variety of fractured carbonate formations,and the change of the wettability of the matrix,which is a desirable behavior in a huff and puff process,as reported in a previous publication about a successful pilot test of this foam.

关 键 词：Calcium chelation Foaming composition Supramolecular surfactant Molecular design Gas mobility control Flow assurance Improved oil recovery Conformance control 

分 类 号：TE328[石油与天然气工程—油气田开发工程]