烯烃齐聚催化剂的研究进展  

Research Progress of Olefin Oligomerization Catalyst

作　　者：卢琪 肖林久[1,2] 刘蝈蝈 李文泽 LU Qi;XIAO Lin-jiu;LIU Guo-guo;LI Wen-ze(College of Science,Shenyang University of Chemical Technology,Shenyang 110142,China;Liaoning Key Laboratory of Rare Earth Chemistry and Application,Shenyang 110142,China)

机构地区：[1]沈阳化工大学理学院,沈阳110142 [2]辽宁省稀土化学及应用重点实验室,沈阳110142

出　　处：《当代化工》2020年第11期2602-2610,2614,共10页Contemporary Chemical Industry

基　　金：辽宁省教育厅科学研究经费项目,用于低浓度二氧化碳捕集和转化利用的多孔基底负载多氮腔环复合材料的研究(项目编号:LZ2019005)

摘　　要：阐述各类烯烃齐聚反应所应用的不同类型催化剂,归纳分析对短链烯烃(C2、C3)、中等链长烯烃(1-丁烯、异丁烯)以及长链烯烃(以1-癸烯为代表)进行齐聚反应适用的催化剂以及助催化剂。结果表明:固相催化剂不需要价格昂贵的助催化剂活化,而均相催化剂必须经过助催化剂活化才可表现出催化活性;乙烯齐聚催化剂多采用过渡金属配合物以及H型分子筛,丁烯低聚采用固体酸催化剂或离子液体等,1-癸烯采用茂金属、Lewis酸、离子液体进行聚合,最后对烯烃齐聚反应的发展前景进行了展望。The different types of catalysts used in the oligomerization of various olefins were described.The catalysts and cocatalysts suitable for the oligomerization of short chain olefins(C2,C3),medium chain olefins(1-butene,isobutylene)and long chain olefins(1-decene)were analyzed,and it was concluded that solid phase catalysts do not require expensive cocatalyst activation,and homogeneous catalysts must undergo cocatalyst activation to exhibit catalytic activity;ethylene oligomerization catalysts mostly use transition metal complexes and H-type molecular sieves,butene oligomerization uses solid acid catalysts or ionic liquids and so on,1-decene uses metallocene,Lewis acid and ionic liquids for polymerization.Finally,the development trend of olefin oligomerization was prospected.

关 键 词：烯烃齐聚 研究进展 低聚反应 选择性 

分 类 号：TQ316.3[化学工程—高聚物工业] TQ426