锰氧化物中氧空位的构建及其催化氧化苯系物作用机制研究进展  

Research Progress on the Construction of Oxygen Vacancies in Manganese Oxides and the Mechanism of Their Catalytic Oxidation of Benzene Series

作　　者：廖伟 陆继长[1,2,3] 张迎 刘江平 罗永明[1,2,3,4] 朱文杰 LIAO Wei;LU Ji-chang;ZHANG Ying;LIU Jiang-ping;LUO Yong-ming;ZHU Wen-jie(Faculty of Environmental Science and Engineering,Kunming University of Science and Technology,Kunming 650500,China;The Innovation Team for Volatile Organic Compounds Pollutants Control and Resource Utilization of Yunnan Province,Kunming 650500,China;The Higher Educational Key Laboratory for Odorous Volatile Organic Compounds Pollutants Control of Yunnan Province,Kunming 650500,China;Faculty of Chemical Engineering,Kunming University of Science and Technology,Kunming,650093,China)

机构地区：[1]昆明理工大学环境科学与工程学院,云南昆明650500 [2]昆明理工大学挥发性有机物污染防治与资源化省创新团队,云南昆明650500 [3]云南省高校恶臭挥发性有机物控制重点实验室,云南昆明650500 [4]昆明理工大学化学工程学院,云南昆明650093

出　　处：《分子催化》2022年第5期467-479,共13页Journal of Molecular Catalysis(China)

基　　金：国家自然科学基金(22166021);云南省科技厅科技计划项目(202001AT070035);云南省教育厅科学研究基金项目(2020J0060);云南省基础研究计划项目(140520210099,140520210018)

摘　　要：作为一种过渡金属氧化物,锰氧化物以其多晶型、储/释氧能力强、蕴含丰富氧物种、结构缺陷可控等优点被广泛应用于苯系物的热催化氧化.其中,具有众多特性的氧空位能有效促进苯系物的完全催化氧化,因而成为各界研究的焦点.我们综述了常见的氧空位构建方法及表征技术,并总结了在苯系物催化氧化过程中,锰氧化物中氧空位的几种重要作用机制对催化活性和抗水性能的积极影响.最后对氧空位构建新方法、形成机理、具体过程及其在锰氧化物热催化氧化苯系物领域中的应用进行了总结和展望.With its merits of polymorphism,strong oxygen storage/release capacity,rich oxygen species and controllability of structural defects,manganese oxide,a transition metal oxide,is frequently utilized in the thermal catalytic oxidation of benzene series.Thereinto,oxygen vacancies(OVs)with many characteristics have attracted the attention of researchers from various circles because they can efficiently promote the complete catalytic oxidation of benzene series.We reviewed the common construction methods and characterization techniques of OVs,and summarized the positive effects of several important mechanisms of OVs in manganese oxide on catalytic activity and water resistance in the catalytic oxidation of benzene series.Finally,this research concludes by summarizing and predicting novel techniques,creation mechanisms,particular processes and their applications in the area of benzene series thermocatalytic oxidation by manganese oxide.

关 键 词：锰氧化物 氧空位构建 苯系物 吸附及活化 晶格氧迁移 价态转变 

分 类 号：X701[环境科学与工程—环境工程] TQ426[化学工程]