钯-膦-酸体系催化烯烃氢酯基化反应研究进展  

Research Progress of Alkene Hydroesterification Catalyzed by Palladium-phosphine-acid System

作　　者：鲁艳梅 兰永成 郧栋 夏春谷[1] 刘建华[1] LU Yan-mei;LAN Yong-cheng;YUN Dong;XIA Chun-gu;LIU Jian-hua(State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics(LICP),Chinese Academy of Sciences,Lanzhou 730000,China;University of Chinese Academy of Sciences,Beijing 100049,China)

机构地区：[1]中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室,甘肃兰州730000 [2]中国科学院大学,北京100049

出　　处：《分子催化》2022年第4期360-373,共14页Journal of Molecular Catalysis(China)

基　　金：国家自然科学基金项目(No.22072166,21673260);中国科学院“西部之光”—“西部青年学者”项目A类

摘　　要：烯烃氢酯基化反应是羰基合成领域的重要分支之一,长期以来一直备受关注.目前已发展了钯基、铑基、钴基、钌基等众多催化体系,其中钯-膦-酸催化体系因具有反应条件温和、底物普适性良好、催化性能优异等优点而得到最广泛、最深入的研究.因此,我们对均相、非均相的钯-膦-酸催化体系在烯烃氢酯基化反应中的研究应用进行了综述,并对催化机理、催化剂组成和性能进行了讨论,最后指出稳定性高、可回收性好的非均相钯-膦-酸催化体系将是该领域的研究重点.Alkene hydroesterification is an important branch of carbonyl synthesis,which has attracted much attention for a long time.At present,Pd based,Rh based,Co based,Ru based and other catalytic systems have been developed.Among them,palladium-phosphine-acid system has been the most widely and deeply studied because of its mild reaction conditions,good substrate universality and excellent catalytic performance.Therefore,the research and application of homogeneous and heterogeneous palladium-phosphine-acid catalytic system in alkene hydroesterification are briefly reviewed,and the catalytic mechanism,catalyst composition and performance are discussed.Finally,it is pointed out that the heterogeneous palladium-phosphine-acid catalytic system with high stability and good recoverability will be the research focus in this field.

关 键 词：氢酯基化 钯-膦-酸催化体系 负载型催化剂 两相体系 

分 类 号：TQ225.24[化学工程—有机化工] TQ426