母体苯胺六聚体的一步法合成及紫外光谱研究  

Synthesis of Parent Aniline Hexamer via One-step Method and Its UV-Vis Spectral Study

作　　者：陈梁[1] 于有海[1] 毛华平[1] 卢晓峰[1] 张万金[1] 

机构地区：[1]吉林大学麦克德尔米德实验室,长春130012

出　　处：《高等学校化学学报》2004年第3期592-594,396,共4页Chemical Journal of Chinese Universities

基　　金：国家"九七三"计划项目 (批准号 :0 0 1CB610 5 0 5 );重大国际合作项目 (批准号 :2 0 3 2 0 12 0 169)资助

摘　　要：The parent aniline hexamer was synthesized in the emeraldine base(EB) oxidation state through one step oxidative coupling reaction using parent aniline trimer in the leucoemeraldine oxidation state. The hexamer in the EB state was reduced by phenylhydrazine in ethanol and was characterized by IR, 1H NMR , MALDI TOF MS and elemental analysis. The chemical oxidation process of the hexamer was studied by UV Vis spectra. It was found that the hexamer was oxidized to its EB form and then to the pernigraniline oxidation state.The parent aniline hexamer was synthesized in the emeraldine base(EB) oxidation state through one step oxidative coupling reaction using parent aniline trimer in the leucoemeraldine oxidation state. The hexamer in the EB state was reduced by phenylhydrazine in ethanol and was characterized by IR, 1H NMR , MALDI TOF MS and elemental analysis. The chemical oxidation process of the hexamer was studied by UV Vis spectra. It was found that the hexamer was oxidized to its EB form and then to the pern...

关 键 词：氧化偶联反应 聚苯胺 母体苯胺六聚体 

分 类 号：O657.3[理学—分析化学]