低价钛引起的芳酮肟的反应  

Reaction of Aromatic Ketoxime Induced by Low-valent Titanium

作　　者：史达清[1] 赵红[1] 王香善[1] 屠树江[1] 

机构地区：[1]徐州师范大学化学系,徐州221009

出　　处：《有机化学》2004年第2期216-218,117,共4页Chinese Journal of Organic Chemistry

基　　金：江苏省教育厅自然科学基金 (No.0 0 1KJB1 50 0 0 8)资助项目

摘　　要：在低价钛试剂 (TiCl4/Sm)作用下取代苯乙酮肟发生脱肟反应生成酮 ,而在同样条件下 ,二芳酮肟则生成二芳酮。When substituted phenyl methyl ketoximes were treated with low valent titanium (TiCl 4/Sm) the deoximation reaction giving ketones in high yields took place, whereas in the case of diaryl ketoximes, diaryl ketones, amines or Schiff bases were formed.

关 键 词：低价钛试剂 芳酮肟 脱肟 

分 类 号：O621.25[理学—有机化学]