二[N,N-(1,5-亚戊基)氨荒酸]二氯化锡和二(对氟苄基)氯化锡N,N-(1,5-亚戊基)氨荒酸酯的合成、表征及晶体结构  

Synthesis, Characterization and Crystal Structures of Dichlorotin Bis[N,N (1,5-pentylene)]dithiocarbamate and Chlorodi(p-fluorobenzyl)tin N,N-(1,5-pentylene)dithiocarbamate

作　　者：尹汉东[1] 周忠香[1] 

机构地区：[1]聊城大学化学系,聊城252059

出　　处：《有机化学》2004年第2期239-244,118,共7页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金 (No.2 0 2 71 0 2 5);教育部骨干教师基金;山东省自然科学基金 (No.Y2 0 0 1B0 2 )资助项目

摘　　要：合成了二 [N ,N ( 1,5 亚戊基 )氨荒酸 ]二氯化锡和二 (对氟苄基 )氯化锡N ,N ( 1,5 亚戊基 )氨荒酸酯 .用X射线单晶衍射测定了这两个化合物的晶体结构 .化合物 1为单斜晶系 ,空间群P2 1 ,a =0 863 5 ( 5 )nm ,b =0 8842 ( 5 )nm ,c =1 2 942 ( 7)nm ,β =10 2 177( 9)° ,Z =2 ,V =0 965 9( 9)nm3 ,Dc=1 719g/cm3 ,μ =2 0 2 4mm-1 ,R =0 0 42 8,wR =0 0 918.化合物 2正交晶系 ,空间群Pbca ,a =1 3 616( 13 )nm ,b =1 1679( 11)nm ,c =2 760 3 ( 3 )nm ,Z =8,V =4 3 89( 7)nm3 ,Dc=1 612g/cm3 ,μ =1 498mm-1 ,R =0 0 3 5 5 ,wR =0 0 887.在化合物 1中 ,锡原子呈六配位畸变八面体构型 ,化合物Two organotin compounds with [ N,N (1,5 pentylene)]dithiocarbamate, dichlorotin bis[ N,N (1,5 pentylene)]dithiocarbamate (1) and chlorodi( p fluorobenzyl)tin N,N (1,5 pentylene)dithiocarbamate (2), have been synthesized. The crystal structures have been determined by X ray single crystal diffraction. A crystal of the compound 1 is monoclinic with space group P2 1, a =0 8635(5) nm, b =0 8842(5) nm, c =1 2942(7) nm, β =102 177(9), Z =2, V =0 9659(9) nm 3, D c...

关 键 词：二(对氟苄基)二氯化锡 N N-(1 5-亚戊基)氨荒酸酯 合成 晶体结构 

分 类 号：O627[理学—有机化学]