铜催化交叉偶联反应研究的新进展  

Recent Progress in Copper-Catalyzed Cross-Coupling Reactions

作　　者：邓维[1] 刘磊[1] 郭庆祥[1] 

机构地区：[1]中国科学技术大学化学系,合肥230026

出　　处：《有机化学》2004年第2期150-165,114,共17页Chinese Journal of Organic Chemistry

摘　　要：对Cu催化交叉偶联反应的最新研究进展作了综述 .该反应涉及碳—碳、碳—氮、碳—氧、碳—硫、碳—硒、以及碳—卤的成键 .反应的类型包括Ullmann反应、Suzuki反应、Stille反应以及Heck反应等 .还详细地介绍了Cu催化交叉偶联反应中选用不同的铜盐。The cross coupling reaction of unsaturated carbons is one of the most important methods in organic synthesis. It has been widely used in the manufactures of dyes, pharmaceuticals, polymers, and many other fine chemicals. Due to their low price and toxicity, Cu salts have recently emerged as novel catalysts in cross coupling reactions of unsaturated carbons, whose replacement of toxic and expensive Pd or Ni catalysts will greatly improve the chemical industry in both the economic and environmental aspects....

关 键 词：CU催化剂 交叉偶联反应 绿色化学 

分 类 号：O643.3[理学—物理化学]