ELECTROCHEMICAL COPOLYMERIZATION OF DIBENZOFURAN AND 3-METHYLTHIOPHENE IN BORON TRIFLUORIDE DIETHYL ETHERATE  

作　　者：Zhou, Wei-qiang Xu, Jing-kun Wei, Zhen-hong Pu, Shou-zhi 

机构地区：[1]Jiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Organ Chem, Nanchang 330013, Peoples R China [2]Yichun Univ, Inst Coordinat Catalysis, Yichun 336000, Peoples R China

出　　处：《Chinese Journal of Polymer Science》2008年第1期81-90,共10页高分子科学（英文版）

基　　金：This work was financially supported by the Natural Science Foundation of China(Nos.50663001,20564001);Ministry of Education(No.2007-207058).

摘　　要：The copolymerization of dibenzofuran(DBF)and 3-methylthiophene(MET)was successfully achieved electrochemically by direct anodic oxidation of the monomer mixtures in boron trifluoride diethyl etherate.The effects of applied polymerization potential and the monomer concentration ratios on the copolymerization were investigated by linear sweep voltammetry and cyclic voltammetry(CV).The structure of copolymer films were investigated by UV-Vis,infrared spectroscopy,thermal analysis.As-formed novel copolymers own...The copolymerization of dibenzofuran(DBF)and 3-methylthiophene(MET)was successfully achieved electrochemically by direct anodic oxidation of the monomer mixtures in boron trifluoride diethyl etherate.The effects of applied polymerization potential and the monomer concentration ratios on the copolymerization were investigated by linear sweep voltammetry and cyclic voltammetry(CV).The structure of copolymer films were investigated by UV-Vis,infrared spectroscopy,thermal analysis.As-formed novel copolymers own...

关 键 词：Electrochemical copolymerization Poly（dibenzofuan） POLYTHIOPHENES Boron trifluoride diethyl etherate Fluorescence properties 

分 类 号：O621.2[理学—有机化学]