[Co(aipamp)(amp)Cl][ZnCl_4]配合物的晶体结构解析  

Crystal Structure of One Isomer in [Co(aipamp)(amp)Cl][ZnCl_4]System

作　　者：温祖标[1] 郭辉瑞[2] 

机构地区：[1]江西师范大学化学化工学院,江西南昌330022 [2]宜春学院配位催化研究所,江西宜春336000

出　　处：《复旦学报（自然科学版）》2006年第6期689-693,共5页Journal of Fudan University：Natural Science

基　　金：贵州省自然科学基金资助项目(003060);贵州省省长基金资助项目(20013004)

摘　　要：用过氧化物分解法合成得到了[Co(aipamp)(amp)Cl][ZnCl4](aipamp=2-[(2-氨异丙基)氨基甲基]呲啶,amp=2-(氨甲基)吡啶)配合物,晶体学参数：三斜晶系,空间群Pi,a=0．995 7(2),b=1．020 7(3),C=1．147 8(3)nm,α=102,584(5)°,β=91．559(5)°,γ=98．462(5)°,V=1．124 0(5)nm3,Dc=1．699 g·cm-3,Z=2,F000=580,R=0．044 9,ωR=0．098 4；晶胞中含2个配合物阳离子,2个[ZnCl4]2-阴离子；异构体中co3+为六配位,且配合物阳离子中具有C—H…π结构．The complex of[Co(aipamp)(amp)C1][Znck]was synthesized(aipamp=2-[(2-aminoisopropyl)aminomethyl]pyridine,amp=2-(Aminomethyl)pyridine),by decomposing per-oxide complexes．The crystal structureOf the[Co(aipamp)(amp)C1][ZnCh]with C—H…π structure had been determined by single crystal X-ray diffractionmethod．The crystal of the[CO(aipamp)(amp)C1][ZnCh]belongs tO triclnic system with space group Pi,a。0．995 7(2),6=1．020 7(3),c=1．147 8(3)nin,α=102．584(5)°,β=91．559(5)°,γ=98．462(5)°,V=1．124 0(5)nm3,Dc=1．699 g·cm-3,Z=2,F...

关 键 词：钴(III)配合物 晶体结构 C一H…π结构 

分 类 号：O641.4[理学—物理化学]