萜烯马来酸酐催化加氢反应的研究  

Study on Catalytic Hydrogenation of Terpinene Maleic Anhydride

作　　者：孔振武[1] 汪浩[2] 杜予民[2] 储富祥[1] 

机构地区：[1]中国林业科学研究院林产化学工业研究所,国家林业局林产化学工程重点开放性实验室,江苏南京210042 [2]武汉大学资源与环境科学学院,湖北武汉430072

出　　处：《林产化学与工业》2006年第4期48-50,共3页Chemistry and Industry of Forest Products

基　　金：国家杰出青年基金资助项目(30325031)

摘　　要：研究了反应温度、压力、催化剂用量等因素对萜烯马来酸酐催化加氢制备氢化萜烯马来酸酐合成工艺的影响.实验结果表明,采用钯碳催化萜烯马来酸酐加氢生成氢化萜烯马来酸酐的最佳反应条件为:反应温度150～160 ℃、氢气压力8～10 MPa、催化剂用量4 %～6 %.该催化氢化工艺具有催化效率高、选择性好、反应时间短等优点.Hydrogenated terpinene maleic anhydride was prepared by catalytic hydrogenation of terpinene maleic anhydride in the presence of Pd/C catalyst. The affecting factors of hydrogenation, such as temperature, pressure and dosage of catalyst, were investigated. Hydrogenated terpinene maleic anhydride could be obtained in a short time with high reaction selectivity and conversion ratio by hydrogenation of terpinene maleic anhydride at reaction temperature from 150 to 160℃ , pressure from 8 to 10MPa and the dosage of catalyst from 4% to 6% .

关 键 词：萜烯马来酸酐 催化氢化 

分 类 号：TQ351.47[化学工程]