铽与邻氨基苯基苯甲酸配合物的合成、表征及荧光性质  

Syntheses,Characterization and Fluorescence Properties of Complexes of Terbium with Ortho-Amino Phenylbenzoic Acid

作　　者：王少亭[1] 邓玉恒[1] 张帆[1] 杨永丽[1] 

机构地区：[1]首都师范大学化学系,北京100037

出　　处：《中国稀土学报》2006年第z2期113-115,共3页Journal of the Chinese Society of Rare Earths

基　　金：北京市科技新星计划(H013610050112);北京市教委项目(2002KJ094)

摘　　要：选择不同的pH值,在乙醇-水溶液中合成了铽与邻氨基苯基苯甲酸固体配合物。通过元素分析、摩尔电导、热分析、红外光谱、紫外光谱,表征并确定了配合物的化学组成为TbL4K.nH2O(n=1,2)。同时,在不同pH值下合成得到的配合物的荧光性质也得到了测试和讨论,表明pH=10.0时配合物TbL4K.2H2O在544 nm处5D4→7F5跃迁的发射峰为最强。The solid complexes of terbium with ortho-amino phenylbenzoic acid(HL) were synthesized at different pH values in the ethanol-water mixed solvent in this paper.The chemical composition of complexes is confirmed to be TbL_4K·nH_2O(n=1,2) by the element analysis,molar conductivity,DTA-TGA,infrared and ultraviolet spectra.Meanwhile the fluorescent properties of the complexes formed at the different pH values were measured and investigated.The results show that the emission peak of()~5D_4→~7F_5 transition is the strongest at 544 nm in complex TbL_4K·2H_2O formed at pH=10.0.

关 键 词：邻氨基苯基苯甲酸 铽配合物 稀土配合物 荧光性质 

分 类 号：O614.33[理学—无机化学]