NEW POLY(METHACRYLATE)S CONTAINING OXIME ESTERS MOIETIES BASED ON CYCLOHEXANON AND CYCLOPENTANON  

作　　者：Ibrahim Erol 

机构地区：[1]Afyon Kocatepe Universty Faculty of Science and Arts,Department of Chemistry,Afyonkarahisar,Turkey

出　　处：《Chinese Journal of Polymer Science》2008年第4期443-454,共12页高分子科学（英文版）

基　　金：Afyon Kocatepe Universty Research Fund(No.06-FENED-09)

摘　　要：The synthesis of two new methacrylates such as 2-[(cyclohexylideneamino)oxy]-2-oxoethyl methylacrylate (CHOEMA)and 2-[(cyclopentylideneamino)oxy]-2-oxoethyl methylacrylate(CPOEMA)are described.The monomers produced from the reaction of corresponding cyclohexanone O-(2-chloroacetyl)oxime and cyclopentanone O-(2- chloroacetyl)oxime with sodium methacrylate was polymerized in 1,4-dioxane solution at 65℃using AIBN as an initiator. The monomers and their polymers were characterized by IR,~1H- and ^(13)C-NMR spec...The synthesis of two new methacrylates such as 2-[(cyclohexylideneamino)oxy]-2-oxoethyl methylacrylate (CHOEMA)and 2-[(cyclopentylideneamino)oxy]-2-oxoethyl methylacrylate(CPOEMA)are described.The monomers produced from the reaction of corresponding cyclohexanone O-(2-chloroacetyl)oxime and cyclopentanone O-(2- chloroacetyl)oxime with sodium methacrylate was polymerized in 1,4-dioxane solution at 65℃using AIBN as an initiator. The monomers and their polymers were characterized by IR,~1H- and ^(13)C-NMR spec...

关 键 词：METHACRYLATE Oxime esters Activation energy Thermal decompositionv Biological activitiy 

分 类 号：O631.3[理学—高分子化学]