Enantioselective Addition of Diethylzinc to Aldehydes Catalyzed by N-Sulfonylated Amino Alcohols  

Enantioselective Addition of Diethylzinc to Aldehydes Catalyzed by N-Sulfonylated Amino Alcohols

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作  者:HUI,Xin-Ping XU,Peng-Fei GAU,Han-Mou 

机构地区:[1]State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000 State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000 Department of Chemistry, National Chung-Hsing University, Taichung, Taiwan

出  处:《有机化学》2004年第z1期172-,共1页Chinese Journal of Organic Chemistry

基  金:Project supported by the Natural Science Foundation of Gansu Province (No. YS-011-A25-001).

摘  要:  Asymmetric C-C bond forming reactions are of prime importance in modem synthetic organic chemistry. The use of chiral amino alcohol ligands is widespread in this area.[1] Herein, we describe the synthesis of N-sulfonylated amino alcohols 1~4 and enantioselective addition of diethylzinc to aldehydes was carried out employing titanium(Ⅳ) complexes 1~4.……

分 类 号:O62[理学—有机化学]

 

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