Synthesis of the Anionic Fluororeceptors and Recognition Property for α,ω-Dicarboxylate  

作　　者：HE,Yong-Bing WU,Jin-Long MENG,Ling-Zhi QIN,Hai-Juan 

机构地区：[1]Department of Chemistry, Wuhan University, Hubei 430072 Department of Chemistry, Wuhan University, Hubei 430072 Department of Chemistry, Wuhan University, Hubei 430072 Department of Chemistry, Wuhan University, Hubei 430072

出　　处：《有机化学》2004年第z1期275-,共1页Chinese Journal of Organic Chemistry

基　　金：Project supported by the National Natural Science Foundation of China (No. 20372054).

摘　　要：　　Anions, especially dicarboxylates, play an important role in chemical and biological processes,[1] dicarboxylates are critical components of numerous metabolic processes including, for instance, the citric acid and glyoxylate cycles.[1a]They also play an important role in the generation of high-energy phosphate bonds and in the biosynthesis of important intermediates.[1b] To date, several receptors containing different functional groups for selective binding of dicarboxylate anions have been reported.[2,3] However, the sensors based on the fluorescence emission for dicarboxylate anions are still rare.3 In this paper, we report the synthesis and binding properties of two new neutral anion receptors (1 and 2).……

分 类 号：O62[理学—有机化学]