六氢苯甲酸-环己酮肟联产己内酰胺组合工艺中酰胺液成分的气相色谱-质谱分析  

Determination of GC - MS Method for Compounds in Caprolactam Produced From Cyclohexanecarboxylic Acid - Cyclohexanone, Oxime Process

作　　者：王秀君[1] 潘九海[1] 赵承军[1] 孙东升 于广欣[1] 

机构地区：[1]石家庄炼油厂研究所,河北石家庄050032

出　　处：《分析测试学报》2004年第z1期284-286,共3页Journal of Instrumental Analysis

摘　　要：　　石家庄化纤公司己内酰胺装置是以甲苯为原料,经氧化、加氢、酰胺化、中和、萃取及精制等工序的装置.其基本工艺技术从意大利引进.由于工艺本身的特点,副产物硫铵达3.8吨/吨己内酰胺.该装置设计年产硫氨19万吨,产量较大.……The capillary column gas chromatography was introduced for the determination of the impurities in caprolactam, and the impurity sorts at cyclohexanecarboxylic acid - cyclohexanone. Qxime process and the toluene process were analyzed by gas chromatography - mass spectrometry. The qualitative analysis of the intermediates was conducted.

关 键 词：Cyclohexanecarboxylic acid -cyclohexanone Oxime process CAPROLACTAM GC-MS 

分 类 号：O657-55[理学—分析化学]