铜类催化漆酚氧化聚合成膜的红外研究  

IR Research of the Oxidative Polymerization of Urushiol to Coating Catalyzed by Cupric Complexes with Models of Laccase

作　　者：郭庆宇[1] 

机构地区：[1]湖北省化学研究院生漆研究所

出　　处：《中南民族大学学报（自然科学版）》2003年第S1期103-105,共3页Journal of South-Central University for Nationalities：Natural Science Edition

摘　　要：　用红外光谱研究了铜-吡啶络合物;铜-聚-4-乙稀基吡啶络合物和铜-氯化苄部分季铵盐化的聚4-乙烯基吡啶络合物催化漆酚氧化聚合交联过程.红外光谱变化表明这3种催化剂都模拟了漆酶的催化作用,并各有特点,催化有异同.The oxidative polymerization and crosslinking process of urushiol catalyzed by cupric complexes with pyridine poly{4vinylpyridine} and partially quaternized poly[4vinylpyridine] by benzyl chloride were studied by IR analysis. During oxidative polymerization of urushiol absorption peaks of urushiol change in IR spectrs showed that abovementioned three catalysts simulated the catalytical action of Laccase.

关 键 词：漆酚 模拟漆酶 铜-吡啶类络合物 红外光谱 

分 类 号：O657.33[理学—分析化学]