松香型阳离子乳化剂的制备及性能  

Preparation and performance of cationic emulsifier based on rosin

作　　者：张光华[1] 解攀[1] 刘静[1] 李慧[1] 

机构地区：[1]陕西科技大学化学与化工学院,陕西西安710021

出　　处：《化工进展》2008年第10期1628-1631,1636,共5页Chemical Industry and Engineering Progress

摘　　要：为探索一种优化的松香型阳离子乳化剂生产工艺,以松香、三甲胺与环氧氯丙烷为原料,采用单变量考察的方法探索了反应物配比、反应时间、温度、溶剂对阳离子松香酯化率的影响,研究表明,乙醇为溶剂,n(松香)∶n(三甲胺)∶n(环氧氯丙烷)=1.1∶1∶1,反应温度为100℃,反应时间3.5h的条件下,酯化率可以达到83.4%。用红外光谱以及核磁共振氢谱对目标产物进行了表征,并研究了目标产物的表面性能。结果表明该表面活性剂有良好的表面活性,并对松香有很好的乳化性能。In order to explore an optimized process for preparing a novel cationic emusifier,rosin,trimethylamine and epichlorohydrin as raw materials were used. The influences of reaction parameters on the esterification rate,such as reactants ratio,time,temperature and solvent by means of single-variable parameter. It was indicated that 83.4% of esterification rate could be reached under the optimal conditions as follows:ethanol as reaction solvent,n(rosin)∶n(trimethylamine)∶ n(epichlorohydrin)=1.1∶1∶1,100℃of reacti...

关 键 词：松香 阳离子乳化剂 制备 性能 

分 类 号：TQ423.9[化学工程]