掺杂态聚苯胺蜂窝状有序多孔薄膜的制备及形成机制的探讨  

Fabrication of Ordered Honeycomb Structure Porous Film with Doped Polyaniline and Its Formation Mechanism

作　　者：于春玲[1] 翟锦[2] 高雪峰[2] 万梅香[2] 江雷[2] 李泽生[1] 李铁津 

机构地区：[1]吉林大学化学学院,长春130023 [2]中国科学院化学研究所分子科学中心,北京100080

出　　处：《高等学校化学学报》2004年第7期1322-1324,MJ07,共4页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金重点项目 (批准号 :G19990 64 5 0 4);国家自然科学基金 (批准号 :2 0 12 5 10 2 ;2 0 3 410 0 3 )赞助

摘　　要：Double-layer honeycomb structure of 4-dodecylbenzenesulfonic acid(DBSA)-doped polyaniline(PANI) is fabricated in the humidity atmosphere by self-assembly method. The driving force of this procedure is capillary force(self-assembly) and the water droplet plays the role as template.The morphology and electric property are studied by atomic force microscope and this honeycomb structure is proved to be electro-active. Additionally, the double layer′s formation mechanism is proposed in the systems while the density of organic solvents is higher than that of water.Double-layer honeycomb structure of 4-dodecylbenzenesulfonic acid(DBSA)-doped polyaniline(PANI) is fabricated in the humidity atmosphere by self-assembly method. The driving force of this procedure is capillary force(self-assembly) and the water droplet plays the role as template.The morphology and electric property are studied by atomic force microscope and this honeycomb structure is proved to be electro-active. Additionally, the double layer′s formation mechanism is proposed in the systems while the density of organic solvents is higher than that of water.

关 键 词：掺杂态聚苯胺 蜂窝状结构 有序多孔薄膜 制备 形成机制 

分 类 号：O633.2[理学—高分子化学] O484[理学—化学]