烯丙基酯合成方法在萜类化合物中的应用研究进展  

Research progress in synthetic method for allylic esters and its application in terpenoid compounds

作　　者：卢言菊[1] 赵振东[1] 古研[1] 陈玉湘[1] 毕良武[1] 隋管华[1] 

机构地区：[1]中国林业科学研究院林产化学工业研究所国家林业局林产化学工程重点开放性实验室,江苏南京210042

出　　处：《现代化工》2008年第S2期383-386,共4页Modern Chemical Industry

基　　金：国家"十一五"科技支撑项目(2007BAD82B01);国家自然科学基金项目(30571466)

摘　　要：作为重要聚合物单体或反应性中间体使用的烯丙基酯类化合物,其合成方法主要包括醇酸脱水直接酯化法、酰氯化醇解酯化法、酯(盐)酯交换酯化法、羧酸盐烯丙基卤化物交换酯化法(无机碱催化和有机胺/季铵盐相转移催化)等。以马来松香烯丙醇酯、松香烯丙醇酯、脱氢枞酸烯丙醇酯、蒎酸二烯丙基酯等的合成作为应用实例,综述了烯丙基酯合成方法在萜类化合物中的研究及应用进展,指出相转移催化法是合成萜类烯丙基酯化合物的有效方法之一。Allylic esters,which are often used as important monomers or reactive intermediates in organic synthesis,are mainly synthesized through methods such as directive esterification between carboxylic acid and alcohol,alcoholysis of acyl chloride,transesterification between ester and ester(or salt),as well as esterification between carboxylic salt and allyl halide catalyzide by an organic base or an organic amine or a quaternary ammonium salt as phase transfer catalysts.The research progress in synthetic methods...

关 键 词：烯丙基酯 萜类化合物 合成方法 

分 类 号：TQ351[化学工程]