α-氨基吡啶缩水杨醛希夫碱-邻菲罗啉过渡金属配合物的合成及表征  

Synthesis and characterization of the transition-metallic complex with a phenanthroline and a schiff base ligand derived from α-amino pyridine and salicylaldehyde

作　　者：解庆范[1] 李晓玲[2] 

机构地区：[1]泉州师范学院化学与生命科学学院,福建泉州362000 [2]河南洛阳师范学院化学与化工学院,河南洛阳471022

出　　处：《化学工程与装备》2008年第9期14-18,共5页Chemical Engineering & Equipment

摘　　要：利用α-氨基吡啶和水杨醛合成的杂环Schiff碱,再结合邻菲罗啉合成钴Co(Ⅱ)、镍Ni(Ⅱ)的配合物,并对其进行了元素分析、红外、紫外、热重-差热、电导率等表征,确定了它们的组成分别为[CoL(Phen)NO3]和[NiL(Phen)NO3],其中HL=C12H10ON2。Two transition metal Co(Ⅱ),N(iⅡ)complexes were preparied with the phenanthroline and the schiff base digands derived from α-amino pyridine and salicylaldehyde,and their structure were characterized by element analysis,IR,UV-Vis,molar conductivity and thermal analysis.Their Composition were CoL(Phen)NO3 and NiL(Phen)NO3(HL is C12H10ON2).

关 键 词：希夫碱 邻菲罗啉 过渡金属 合成 表征 

分 类 号：O641.4[理学—物理化学]