EFFECT OF MORPHOLOGICAL STRUCTURE OF AMINOMETHYL POLYSTYRENE RESIN ON THE CATALYTIC PROPERTIES OF POLYMERSUPPORTED RUTHENIUM COMPLEXES  

作　　者：雷自强 

机构地区：[1]Key Laboratory of Polymer Materials of Gansu Province,College of Chemistry and Chemical Engineering,Northwest Normal University

出　　处：《Chinese Journal of Polymer Science》2009年第1期93-100,共8页高分子科学（英文版）

基　　金：supported by the National Natural Science Foundation of China (Nos.20174031 and 20674063);Specialized Research Fund for the Doctoral Program of Higher Education (No.20050736001).;the Key Laboratory of Eco-Environment-Related Polymer Materials (Northwest Normal University);Ministry of Education,for financial support.

摘　　要：Polymer-supported ruthenium complexes ■-Phen-Ru-①,■-Phen-Ru-②,■-Phen-Ru-③,■-Phen-Ru-④, ■-Phen-Ru-⑤,■-Phen-Ru-⑥and ■-Phen-Ru-⑦were prepared using aminomethyl polystyrenes of different morphological structures as supports.A variety of alcohols were oxidized efficiently into the corresponding ketones, carboxylic acids or aldehydes with iodosylbenzene (PhIO) catalyzed by aminomethyl polystyrene-supported ruthenium complexes under mild reaction conditions in acetonitrile.The influences of morphological structure...Polymer-supported ruthenium complexes ■-Phen-Ru-①,■-Phen-Ru-②,■-Phen-Ru-③,■-Phen-Ru-④, ■-Phen-Ru-⑤,■-Phen-Ru-⑥and ■-Phen-Ru-⑦were prepared using aminomethyl polystyrenes of different morphological structures as supports.A variety of alcohols were oxidized efficiently into the corresponding ketones, carboxylic acids or aldehydes with iodosylbenzene (PhIO) catalyzed by aminomethyl polystyrene-supported ruthenium complexes under mild reaction conditions in acetonitrile.The influences of morphological structure...

关 键 词：Alcohol oxidation Ru-immobilized catalyst PS-carrier Morphological structure 

分 类 号：O634[理学—高分子化学]