全馏分催化裂化汽油临氢芳构化研究  

Study on hydroaromatization of full-range FCC gasoline

作　　者：赵立祥[1] 高媛[1] 王海彦[1] 魏民[1] 施岩[1] 庞舒[2] 

机构地区：[1]辽宁石油化工大学石油化工学院,辽宁抚顺113001 [2]中国石油抚顺石化公司腈纶化工厂,辽宁抚顺113109

出　　处：《工业催化》2009年第6期35-38,共4页Industrial Catalysis

摘　　要：程序升温还原法制备了MoP/HZSM-5催化剂,并进行了XRD表征。以催化裂化全馏分油为原料,在小型连续固定床反应装置上,考察了工艺条件对催化剂芳构化降烯烃性能的影响。结果表明,MoP/HZSM-5催化剂具有较高活性和稳定性。在反应温度380℃、压力2.0MPa、空速1.0 h^(-1)和氢油体积比400:1条件下,芳烃体积分数36.90%,烯烃体积分数26.16%,液收66.70%。MoP-supported HZSM-5 zeolite catalysts were prepared by impregnation and temperature- programmed reduction (TPR) and characterized by XRD.The effects of reaction temperature,pressure, hydrogen/oil volumetric ratio on the aromatization and olefins-reducing results were investigated on a small fixed-bed reactor.The results showed that MoP/HZSM-5 catalyst exhibited high catalytic activity and stability under the following optimum reaction condition:reaction temperature 380 ℃,pressure 2.0 MPa, space velocity 1.0 h^(-1),and hydrogen/oil volumetric ratio 400:1.Aromatics content of 36.90%,olefins content of 26.16% and liqulid yield of 66.70% were obtained over the MoP/HZSM-5 catalyst.

关 键 词：催化化学 MoP/HZSM-5催化剂 催化裂化汽油 芳构化 降烯烃 

分 类 号：O643.36[理学—物理化学] TE624.4+7[理学—化学]