Studies on the phase properties of lyotropic liquid crystals of Brij35/sodium oleate/oleic acid/water system: By means of polarizing microscope, SAXS, 2H-NMR and rheological methods  

作　　者：AN Ya1,2,XU Jun1,ZHANG Jin1,HU Changgang1,2,LI Ganzuo1,WANG Zhining1,WANG Zhongni1,ZHANG Xiaoyi2 & ZHENG Liqiang1 1. Key Lab of Colloid and Interface Chemistry for State Education Ministry,Jinan 250100,China 2. College of Science,Guizhou Normal University,Guiyang 550001,China 

出　　处：《Science China Chemistry》2006年第5期411-422,共12页中国科学（化学英文版）

基　　金：This work was supported by the National Natural Science Foundation of China (Grant No. 30370945) ; Guizhou Provincial Governor Foundation (No. 6, 2001).

摘　　要：The pseudo-quaternary phase diagram of Brij35/sodium oleate/oleic acid/watersystems has been investigated, and the liquid crystal area has been identified, which covers abouttwo thirds of the whole phase diagram. The liquid crystal structure and behavior have been alsostudied by using polarizing texture, small angle X-ray scattering, ~2H-NMR and rheometer etc. Theresult shows that when the composition of the system changes along the line of AA′ in this largeliquid crystal region, the structural change iscubic→cubic/lamellar→lamellar→larnellar/hexagonal→hexagonal. Meanwhile, we made the firstattempt of systematic study of the rheological properties of the above system. The lattice constantsof cubic and hexagonal liquid crystals are 10.53 and 5.68 nm, respectively.The pseudo-quaternary phase diagram of Brij35/sodium oleate/oleic acid/water systems has been investigated, and the liquid crystal area has been identified, which covers about two thirds of the whole phase diagram. The liquid crystal structure and behavior have been also studied by using polarizing texture, small angle X-ray scattering, 2H-NMR and rheometer etc. The result shows that when the composition of the system changes along the line of AA′ in this large liquid crystal region, the structural change is cubic→cubic/lamellar→lamellar→lamellar/hexagonal→hexagonal. Meanwhile, we made the first attempt of systematic study of the rheological properties of the above system. The lattice constants of cubic and hexagonal liquid crystals are 10.53 and 5.68 nm, respectively.

关 键 词：Brij35  LYOTROPIC liquid crystals  2H-NMR  polarizing textures  small ANGLE X-ray scattering  RHEOLOGICAL properties. 

分 类 号：O753.2[理学—晶体学]