SYNTHESIS OF POLYISOBUTYLENE WITH SEC-ARYLAMINO TERMINAL GROUP BY COMBINATION OF CATIONIC POLYMERIZATION WITH ALKYLATION  

作　　者：吴一弦 

机构地区：[1]Beijing University of Chemical Technology,State Key Laboratory of Chemical Resource Engineering

出　　处：《Chinese Journal of Polymer Science》2009年第4期551-559,共9页高分子科学（英文版）

基　　金：supported by the National Natural Science Foundation of China(No.20774008);Ministry of Education(No.IRT0706).

摘　　要：The highly reactive polyisobutylenes(PIBs) withα-double bonds(87.5 mol%) or tert-chloro(tert-Cl) groups(95 mol%) could be prepared via the cationic polymerization of isobutylene(IB) coinitiated by BF_3 or TiCl_4 respectively.The Friedel-Crafts alkylation of diphenylamine(DPA) with the highly reactive PIB withα-double bonds was further conducted under different conditions,such as at different alkylation temperature,in the mixed solvents of CH_2Cl_2/n-hexane with different solvent polarity and at DPA concentr...The highly reactive polyisobutylenes(PIBs) withα-double bonds(87.5 mol%) or tert-chloro(tert-Cl) groups(95 mol%) could be prepared via the cationic polymerization of isobutylene(IB) coinitiated by BF_3 or TiCl_4 respectively.The Friedel-Crafts alkylation of diphenylamine(DPA) with the highly reactive PIB withα-double bonds was further conducted under different conditions,such as at different alkylation temperature,in the mixed solvents of CH_2Cl_2/n-hexane with different solvent polarity and at DPA concentr...

关 键 词：POLYISOBUTYLENE Cationic polymerization DIPHENYLAMINE ALKYLATION 

分 类 号：O631.3[理学—高分子化学]