SYNTHESIS,CHARACTERIZATION,THERMAL DEGRADATION AND ELECTRICAL CONDUCTIVITY OF OLIGO[2-(THIEN-2-YLMETHYLENE)AMINOPHENOL]AND OLIGOMER-METAL COMPLEXES  

作　　者：smet Kaya Aysel Aydin 

机构地区：[1]Department of Chemistry,Faculty of Science and Arts,Canakkale Onsekiz Mart University,TR-17020,Canakkale,Turkey

出　　处：《Chinese Journal of Polymer Science》2009年第4期465-477,共13页高分子科学（英文版）

基　　金：supported by the Government Planning Organization(GPO2002K120170-7);TUBITAK GrantsCommission for a research grant(No.TBAG-105T428).

摘　　要：The optimum reaction conditions of the oxidative polycondensation of 2-(thien-2-yl-methylene)aminophenol (2-TMAP) has been accomplished by using air O_2,H_2O_2 and NaOCl oxidants in an aqueous alkaline medium between 20℃and 90℃.The structures of the monomer and oligomer were confirmed by FT-IR,UV-Vis,~1H-NMR and ^(13)C-NMR and elemental analysis.TGA-DTA,size exclusion chromatography(SEC) techniques and solubility tests were applied for characterization.The ~1H-NMR and ^(13)C-NMR data show that the polymeriz...The optimum reaction conditions of the oxidative polycondensation of 2-(thien-2-yl-methylene)aminophenol (2-TMAP) has been accomplished by using air O_2,H_2O_2 and NaOCl oxidants in an aqueous alkaline medium between 20℃and 90℃.The structures of the monomer and oligomer were confirmed by FT-IR,UV-Vis,~1H-NMR and ^(13)C-NMR and elemental analysis.TGA-DTA,size exclusion chromatography(SEC) techniques and solubility tests were applied for characterization.The ~1H-NMR and ^(13)C-NMR data show that the polymeriz...

关 键 词：Air O_2 NAOCL O1igo[2-（thien-2-yl-methylene）aminophenol] Oxidative polycondensation Thermal analysis Electrical conductivity Oligomer-metal complex compounds 

分 类 号：O631.3[理学—高分子化学]