SYNTHESIS AND PHOTOPHYSICAL PROPERTIES OF POLY(ARYL IMINO)CONTAINING ACRIDINE UNITS(PAIA)  

作　　者：张林 

机构地区：[1]Research Center of Laser Fusion,China Academy of Engineering Physics

出　　处：《Chinese Journal of Polymer Science》2009年第6期851-856,共6页高分子科学（英文版）

基　　金：supported by the Foundation of National Key Laboratory of High Temperature and Density Plasma Physics(No.9140C6806030807);the Science and Technology Development Foundation of China Academy of Physics Engineering(No.200708006)

摘　　要：1,4-Bis-(4-bromobenzoyl)benzene and proflavine,3,6-diaminoacridine free base were synthesized first.Using 1,4- bis-(4-bromobenzoyl)benzene and proflavine,3,6-diaminoacridine free base as the monomers,poly(aryl imino) containing acridine units(PAIA) was synthesized via palladium-catalyzed amination.The structure of PAIA was characterized by means of FTIR,~1H-NMR spectroscopy and elemental analysis,the results show an agreement with the proposed structure.The UV absorption and photoluminescence spectra were t...1,4-Bis-(4-bromobenzoyl)benzene and proflavine,3,6-diaminoacridine free base were synthesized first.Using 1,4- bis-(4-bromobenzoyl)benzene and proflavine,3,6-diaminoacridine free base as the monomers,poly(aryl imino) containing acridine units(PAIA) was synthesized via palladium-catalyzed amination.The structure of PAIA was characterized by means of FTIR,~1H-NMR spectroscopy and elemental analysis,the results show an agreement with the proposed structure.The UV absorption and photoluminescence spectra were t...

关 键 词：Poly（aryl imino） Acridine unite Palladium-catalyzed amination PHOTOLUMINESCENCE 

分 类 号：O631.3[理学—高分子化学]