SYNTHESES AND ACTIVE BEHAVIOR OF NOVEL UV PHOTOINITIATORS  

作　　者：阳年发 

机构地区：[1]Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education,College of Chemistry,Xiangtan University

出　　处：《Chinese Journal of Polymer Science》2009年第6期873-877,共5页高分子科学（英文版）

基　　金：supported by the National Natural Science Foundation of China(No.20772102);Doctor Student Research Foundation of Chinese Education Ministry(No.20060530002)

摘　　要：A series of novel hybrid photoinitiators(YPhCOPhXPhI^+PhPF_6^-,Y = 4-NO_2,4-MeO or 3-Cl,X = O,OCH_2,or nothing),which contain multiple aromatic rings(PhCOPhXPh),were prepared by reaction of easily available aryl ketones (YPhCOPhXPh) with iodosobenzene diacetate[PhI^+OCOCH_3(CH_3CO_2)^-].The inset of an aromatic ring into p-benzoyldiphenyliodonium hexafluorophophate(PhCOPhI^+PhPF_6^-)(BDPIH,He-type photoinitiator) between diphenyliodonium and benzoyl is propitious both to the preparation and the photoinitiat...A series of novel hybrid photoinitiators(YPhCOPhXPhI^+PhPF_6^-,Y = 4-NO_2,4-MeO or 3-Cl,X = O,OCH_2,or nothing),which contain multiple aromatic rings(PhCOPhXPh),were prepared by reaction of easily available aryl ketones (YPhCOPhXPh) with iodosobenzene diacetate[PhI^+OCOCH_3(CH_3CO_2)^-].The inset of an aromatic ring into p-benzoyldiphenyliodonium hexafluorophophate(PhCOPhI^+PhPF_6^-)(BDPIH,He-type photoinitiator) between diphenyliodonium and benzoyl is propitious both to the preparation and the photoinitiat...

关 键 词：PHOTOINITIATOR Iodosobenzene diacetate Synthesis 

分 类 号：O621.25[理学—有机化学]