一种新型的稀土Tb配合物的光致和电致发光性能的研究  

Photoluminescent and Electroluminescent Properties of a New Rare Earth Terbium Complex

作　　者：王丽[1] 张希清[1] 林鹏[1] 熊德平[1] 黄世华[1] 俞天智[2] 

机构地区：[1]北京交通大学光电子技术研究所 [2]兰州大学化学化工学院,甘肃兰州730000

出　　处：《光谱学与光谱分析》2004年第6期644-646,共3页Spectroscopy and Spectral Analysis

基　　金：国家自然科学基金 (6960 60 0 1 );教育部留学回国人员科研启动基金(LIC0 30 0 4 )资助项目

摘　　要：用一种新型的含酚羟基的Schiff碱三足配体H3L3稀土Tb配合物作发光层制备了三层结构电致发光器件 ,器件在正向直流偏压下发出明亮的绿光。器件的电致发光 (EL)光谱和Tb配合物薄膜的光致发光(PL)光谱与典型的Tb配合物的发光光谱相同。研究了器件发光及电学特性 。Pure green and narrow bandwidth emission from an organic electroluminescent device was presented by using a new rare earth terbium (III) complex as the emissive layer. The structure of the device was ITO/PVK/Tb/PBD/LiF/Al. It was proved that this new kind of rare earth complex has excellent photoluminescent and electroluminescent properties. The electroluminescent spectrum of the device was very similar to that of the terbium (III) complex film. The electroluminescent mechanism of the device was proposed by measuring and analyzing the spectra and electroluminescent property of the device. It is proposed that the excited carriers of PVK and PBD were captured by Tb3+ and light was emitted when the electrons and holes recombined at Tb3+.

关 键 词：铋配合物 光致发光性能 电致发光性能 SCHIFF碱 发光机理 

分 类 号：O614.341[理学—无机化学] TN383[理学—化学]