Interface and properties of epoxy resin modified by elastomeric nano-particles  

作　　者：HUANG Fan1, LIU Yiqun1, ZHANG Xiaohong1, GAO Jianming1, SONG Zhihai1, TANG Banghui1, WEI Genshuan2 & QIAO Jinliang1 1. SINOPEC Beijing Research Institute of Chemical Industry, Beijing 100013, China 2. Institute of Applied Chemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing 100080, China Correspondence should be addressed to Qiao Jinliang (email: [e-mail].) 

出　　处：《Science China Chemistry》2005年第2期148-155,共8页中国科学（化学英文版）

基　　金：the Special Funds for Major State Bas ic Research Projects(G1999064800); Funds for Nation“863”Projects(2002AA302510)

摘　　要：Study on a new composite of epoxy resin/elastomeric nano-particles (ENP) is re- ported in this paper, which shows that, in comparison with pure epoxy resin and epoxy toughened with CTBN, the composites of epoxy resin/carboxylic nitrile-butadiene ENP and epoxy resin/styrene butadiene vinyl-pyridine ENP possess both higher toughness and heat resistance. Both ENPs used in the study have an average size of less than 100 nm. Study on the epoxy network’s morphology and interface properties suggests that due to the chemical reaction be- tween ENP and epoxy resin and more hydrogen bonds between nitrile groups of the rubber and hydroxyl groups of the epoxy resin, stronger interaction at the larger interface may lead to the observed excellent properties of the epoxy resin toughened with ENP.Study on a new composite of epoxy resin/elastomeric nano-particles (ENP) is re- ported in this paper, which shows that, in comparison with pure epoxy resin and epoxy toughened with CTBN, the composites of epoxy resin/carboxylic nitrile-butadiene ENP and epoxy resin/styrene butadiene vinyl-pyridine ENP possess both higher toughness and heat resistance. Both ENPs used in the study have an average size of less than 100 nm. Study on the epoxy network’s morphology and interface properties suggests that due to the chemical reaction be- tween ENP and epoxy resin and more hydrogen bonds between nitrile groups of the rubber and hydroxyl groups of the epoxy resin, stronger interaction at the larger interface may lead to the observed excellent properties of the epoxy resin toughened with ENP.

关 键 词：ELASTOMERIC nano-particles  epoxy resin  carboxylic nitrile-butadiene rubber  STYRENE BUTADIENE vinyl-pyridine rubber  interface. 

分 类 号：TQ323.5[化学工程—合成树脂塑料工业]