改善钙钛矿材料室温下磁电阻效应的有效途径  

Improvement of Magnetoresistance Effect in Perovskite at Room Temperature

作　　者：黄宝歆[1] 

机构地区：[1]潍坊学院物理系,山东潍坊261061

出　　处：《稀有金属》2010年第1期141-144,共4页Chinese Journal of Rare Metals

基　　金：国家重点基础研究专项经费资助项目(G1998061310);鸢都学者岗位基金资助项目;山东省教育厅研究专项资助项目(J09LA52)

摘　　要：将Ag2O与La0.67Ca0.25Sr0.08MnO3均匀混合经高温烧结后形成La0.67Ca0.25Sr0.08MnO3/xAg两相复合体系。随Ag掺入量的增加,样品的电阻率明显下降,磁化强度有小量下降,TC及电阻率的峰值温度TP没有明显变化。304K温度下,从x=0.25样品中得到最大磁电阻效应,磁电阻比约为41%,分别是La0.67Ca0.25Sr0.08MnO3和La0.67Sr0.33MnO3样品的1.6及10倍。磁电阻的本征效应和传导电子在界面处的自旋相关散射作用是产生室温下增强磁电阻效应的主要原因。结果说明,利用离子的掺杂效应调整居里温度到室温附近,再结合金属/钙钛矿复合体系界面属性丰富的特性来制备庞磁电阻材料是提高室温磁电阻有效的途径,这对应用研究具有十分重要的意义。The composite of La0.67Ca0.25Sr0.08MnO3/xAg was prepared by calcining the mixture of La0.67Ca0.25Sr0.08MnO3 and Ag2O powders. With increasing the dopant amount of Ag,resistivity of the sample decreased obviously,and the magnetization decreased slightly,while both TC and TP (the peak resistance temperature) almost kept unchanged. At 304 K,the maximum magnetoresistance (MR) effect (41%) was obtained for the sample with x=0.25,which was 1.6 times and 10 times bigger than that of La0.67Ca0.25Sr0.08MnO3 and La0....

关 键 词：庞磁电阻 颗粒系统 两相复合体系 自旋相关散射 

分 类 号：O482.5[理学—固体物理]