Synthesis and anion recognition of neutral receptors based on multiamide calix[4]arene  

作　　者：LIU Shunying WANG Fajun WEI Lanhua XIAO Wang MENG Lingzhi HE Yongbing 

机构地区：[1]Department of Chemistry, Wuhan University, Wuhan 430072, China Department of Chemistry, Wuhan University, Wuhan 430072, China Department of Chemistry, Wuhan University, Wuhan 430072, China Department of Chemistry, Wuhan University, Wuhan 430072, China Department of Chemistry, Wuhan University, Wuhan 430072, China Department of Chemistry, Wuhan University, Wuhan 430072, China

出　　处：《Science China Chemistry》2004年第2期145-151,共7页中国科学（化学英文版）

基　　金：This work was supported by the National Natural Science Foundation of China(Grant No.20072029).

摘　　要：Two multiamide calix[4]arenes (5, 6) were synthesized and characterized by NMR, MS and elemental analysis. The binding properties of receptors with some anions (π-O2NPhOPO 3 2? , π-O2NPhO?, H2PO 4 ? , Ac?, Cl?, Br? and I?) were studied by UV-Vis spectra. The results indicate that the tetraamide calix[4]arenes (5, 6) have a good selectivity to the anions containing aromatic ring (π-O2NPhOPO3 2?, π-O2NPhO?). The 1 : 1 complexes between host and guest were formed through multiple hydrogen bonding and π-π interactions. The hosts 5 and 6 also show a definite binding ability for the anions (H2PO 4 ? , Ac?, Cl?) that have no ultraviolet absorption, which provides a simple method of spectrum detection for these anions.Two multiamide calyx[4].arenas(5,6)were synthesized and characterized by IR,1H NMR,MS and elemental analysis.The binding properties of receptors with some anions (p-O2NphOpO2-3,p-O2NphO-,H2PO-4,Ac-,CI-,Br- and I-)Were studied by UV-Vis spectra.The results indicate that the tetraamide calix[4]arenas (5,6) have a good selectivity to the anions containing aromatic ring (p-O2NphOpO2-3,p-O2NphO-).The 1:1 complexes between host and guest were formed through multiple hydrogen bonding and π-π interactions.The hosts 5 and 6 also show a definite binding ability for the anions (H2PO-4,Ac-,CI-) that have no ultraviolet absorption,which provides a simple method of spectrum detection for these anions.

关 键 词：multiple AMIDE arene  NEUTRAL ANION receptor  synthesis  ANION recognition  UV-VIS spectrum. 

分 类 号：O6[理学—化学]