Progress in study on metalloporphyrin mimicking metalloenzymes  

作　　者：JI Liangnian , PENG Xiaobin and HUANG Jinwang( Department of Chemistry, Zhongshan University, Guangzhou 510275,China Department of Applied Chemistry, South China University of Technology, Guangzhou 510641, China) 

出　　处：《Progress in Natural Science:Materials International》2002年第5期321-330,共9页自然科学进展·国际材料（英文版）

基　　金：Supported by the National Natural Science Foundation of China (Grant Nos. 298871036, 29731030, 30070188); State Key Laboratory of Coordination Chemistry in Nanjing University, The Natural Science Foundation of Guangdong Province, and Research Fund of Ro

摘　　要：The development of research on metalloporphyrins, which are used as model compounds for some metalloenzymes, is reviewed, including the survey of oxygen binding of heme, the catalytic oxidation of cytochrome P450, the molecular recognition to amino acid esters, the self-assembly and self-aggregation of metalloporphyrins.The development of research on metalloporphyrins, which are used as model compounds for some metalloenzymes, is reviewed, including the survey of oxygen binding of heme, the catalytic oxidation of cytochrome P450, the molecular recognition to amino acid esters, the self-assembly and self-aggregation of metalloporphyrins.

关 键 词：metalloporphyrins  metalloenzymes  MODEL compound. 

分 类 号：O627[理学—有机化学]