Hydrothermal Synthesis and Characterization of a Novel Supramolecular Network Compound [Co(IN)_2(H_2O)_4](IN=Isonicotinate)  

作　　者：JIA Hong-bin YU Jie-hui DING Hong XU Ji-qing YE Ling JING Wei-jieWANG Tie-gang XU Jia-ning QU Xue-jian LI Zeng-chun 

机构地区：[1]College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry,Jilin University,Changchun 130023,P.R.China [2]Key Laboratory of Supramolecular Structure and Materials of Ministry of Education,Jilin University,Changchun 130023,P.R.China [3]Department of Chemistry,Inner Mongolia University for Nationalities,Tongliao 028000,P.R.China

出　　处：《Chemical Research in Chinese Universities》2002年第4期385-388,共4页高等学校化学研究(英文版)

基　　金：Supported by the National Natural Science Foundation of China( No.2 973 3 0 90 ),the Research Funds for the DoctoralProgram of Higher Education,the State Key L aboratory of Coordination Chemistry;Nanjing U niversity and the Funds ofInner Mongolia Edu

摘　　要：A novel supramolecular compound, [Co(IN)_2(H_2O)_4](1), was synthesized by means of the hydrothermal method and its structure was characterized with elemental analysis, FT-IR spectrum, TGA and X-ray diffraction. Though the unit cell structure of the title compound is only monomeric, all these units as building blocks are assembled into a novel three-dimensional supramolecular network via the widely hydrogen-bonding and π-π stacking interactions.A novel supramolecular compound, [Co(IN)_2(H_2O)_4](1), was synthesized by means of the hydrothermal method and its structure was characterized with elemental analysis, FT-IR spectrum, TGA and X-ray diffraction. Though the unit cell structure of the title compound is only monomeric, all these units as building blocks are assembled into a novel three-dimensional supramolecular network via the widely hydrogen-bonding and π-π stacking interactions.

关 键 词：Hydrothermal synthesis Cobalt(Ⅱ) complex X-Ray diffraction ISONICOTINATE SUPRAMOLECULE 

分 类 号：O641.4[理学—物理化学]