HYDROPHOBICITY OF CONTAMINATED SILICONE RUBBER SURFACES  

作　　者：Zhi-min Zheng Cai-hong Xu Jian Jiang Chang-yu Ren Wei Gao Ze-min Xie Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China 

出　　处：《Chinese Journal of Polymer Science》2002年第6期559-564,共6页高分子科学（英文版）

摘　　要：Silicone rubber (SIR) shows superior performance when used outdoors, but its surface can be transformed from inherently hydrophobic to hydrophilic by the adsorption of contaminants. Al(OH)(3), Al2O3, quartz powder and active carbon were selected as authentic contaminants. Hydrophobicity of the surface was determined using contact angle measurement. The results indicate that the adsorbability of the contaminants can strongly affect the hydrophobicity of contaminated SIR surface. The increasing rate of contact angle of specimens contaminated by Al(OH)(3) was much faster than that by Al2O3 and quartz due to the adsorption of migrated low molecular weight (LMW) polydimethylsiloxanes. Specimens contaminated by active carbon could achieve surface hydrophobicity within 15 min because active carbon has high adsorbability. Surfaces of contaminated ultrapure SIR, polytetrafluoroethylene (PTFE) and glass remain hydrophilic because they contain no mobile LMW components. The addition of oligomeric polydimethylsiloxanes has little effect on the hydrophobicity of contaminants covered on SIR surface.Silicone rubber (SIR) shows superior performance when used outdoors, but its surface can be transformed from inherently hydrophobic to hydrophilic by the adsorption of contaminants. Al(OH)(3), Al2O3, quartz powder and active carbon were selected as authentic contaminants. Hydrophobicity of the surface was determined using contact angle measurement. The results indicate that the adsorbability of the contaminants can strongly affect the hydrophobicity of contaminated SIR surface. The increasing rate of contact angle of specimens contaminated by Al(OH)(3) was much faster than that by Al2O3 and quartz due to the adsorption of migrated low molecular weight (LMW) polydimethylsiloxanes. Specimens contaminated by active carbon could achieve surface hydrophobicity within 15 min because active carbon has high adsorbability. Surfaces of contaminated ultrapure SIR, polytetrafluoroethylene (PTFE) and glass remain hydrophilic because they contain no mobile LMW components. The addition of oligomeric polydimethylsiloxanes has little effect on the hydrophobicity of contaminants covered on SIR surface.

关 键 词：HYDROPHOBICITY silicone rubber contact angle CONTAMINATION 

分 类 号：TQ333.93[化学工程—橡胶工业]