皮革中壬基酚类物质的萃取及GC-MS测定  

Extraction and GC-MS Determination of Nonylphenols in Leather

作　　者：马贺伟[1,2] 许亚萍 徐晔 程伟[1,2] 

机构地区：[1]国家皮革质量监督检验中心,浙江海宁314400 [2]浙江省质量技术监督检测研究院,浙江杭州310013

出　　处：《皮革科学与工程》2010年第5期61-64,共4页Leather Science and Engineering

基　　金：浙江省质量技术监督系统科研计划项目

摘　　要：采用两步法将皮革中的壬基酚(NP)和壬基酚聚氧乙烯醚(NPnEO)分别萃取出来,然后利用GC-MS对两种物质进行测定。第一步采用正己烷对样品中的NP萃取;第二步采用丙酮对样品中NPnEO萃取。索氏抽提和超声波萃取均可作为壬基酚类物质萃取的方式;索氏抽提因作用缓和、萃取物中杂质较少而更适合。采用优化后的萃取方法对皮革样品中壬基酚类物质进行检测,结果表明皮革样品中无NP,但NPnEO含量显著。The nonylphenols(NP) and ethoxylated nonylphenols(NPnEO) in leather were extracted individually by two steps and their contents were tested by GC-MS.The results presented that hexane was suitable for the extraction of NP and acetone was suitable for the extraction of NPnEO.Both Soxhlet and ultrasonic could be used for the extraction of NP and NPnEO in leather.However,Soxhlet was suitable for the extraction due to its mild action.The contents of NP and NPnEO were tested with the optimized extraction method.T...

关 键 词：皮革 壬基酚 聚氧乙烯醚 检测 

分 类 号：TS57[轻工技术与工程—皮革化学与工程]