Attempt to Resolute Chiral Clusters by Optically Active Hydrazide  

作　　者：Yu Hua ZHANG Wei Qiang ZHANG Yu Gang CHEN Zhi CHEN Xin Yi ZHU Huan Wang JING Yuan Qi YIN 

机构地区：[1]State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000

出　　处：《Chinese Chemical Letters》2001年第1期69-70,共2页中国化学快报(英文版)

基　　金：We are grate ful to the National Natural Science Foundation of China for the f inancial support of this work.

摘　　要：A new kind of hydrazone (I) diastereoisomers was prepared with enantiomeric hydazide (II) and chiral cluster (III), which was characterized by HMBC. Unfortunately, the mixture could not be separated into pure diastereoisomer. This could be a direction to separate the racemic chiral clusters.A new kind of hydrazone (I) diastereoisomers was prepared with enantiomeric hydazide (II) and chiral cluster (III), which was characterized by HMBC. Unfortunately, the mixture could not be separated into pure diastereoisomer. This could be a direction to separate the racemic chiral clusters.

关 键 词：Chiral clusters optically active hydrazone chiral resolution DIASTEREOISOMER HMBC. 

分 类 号：O621[理学—有机化学]