(Et_4N)_2[Fe_4(SPh)_10] Stimulated S_(RN)1 Reactions of α-Bromonaphth-alene with Pinacolone Carbanion  

作　　者：Zhao ZHANG Ya Ling GONG Yu WANG Zhao Bin CHEN Pei Lan WANG 

机构地区：[1]Department of Chemistry,Shanxi University,Taiyuan 030006 [2]Test and Analysis Center of Shanxi University,Taiyuan 030006

出　　处：《Chinese Chemical Letters》2001年第2期121-124,共4页中国化学快报(英文版)

基　　金：the Natural Science Fund of Shanxi Province.

摘　　要：The (Et_4N)_2[Fe_4(SPh)_10] stimulated reaction of α-bromonaphthalene with pinacolone carbanion in DMSO leads to the formation of 1-(α-naphthyl)pinacolone. The reaction is suggested in terms of SRN1 mechanism of aromatic nucleophillic substitution and has potential value in synthesis to obtain (-substituted naphthalene derivaties.The (Et_4N)_2[Fe_4(SPh)_10] stimulated reaction of α-bromonaphthalene with pinacolone carbanion in DMSO leads to the formation of 1-(α-naphthyl)pinacolone. The reaction is suggested in terms of SRN1 mechanism of aromatic nucleophillic substitution and has potential value in synthesis to obtain (-substituted naphthalene derivaties.

关 键 词：SRN1 reaction naphthalene derivative pinacolone carbanion nucleophilic substitution. 

分 类 号：O614[理学—无机化学]