A Study on 4,4′-Diaminobenzene Sulfonanilide(DABSA) and the Properties of Dyes Derived from DABSA  

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作  者:WU Zu-Wang 

出  处:《Chemical Research in Chinese Universities》2001年第1期77-87,共11页高等学校化学研究(英文版)

摘  要:A single crystal of 4,4′ diaminobenzene sulfonanilide(DABSA) was determined by X ray diffraction method. It is shown that the two benzene rings are non planar with an angle of 55 1°. Owing to the non planar configuration, the dyes derived from DABSA possess a lower substantivity on fiber but better permeability in substrate, the color of these azo dyes could be matched by two individual azo dyes locating on both sides of the DABSA molecule.A single crystal of 4,4′ diaminobenzene sulfonanilide(DABSA) was determined by X ray diffraction method. It is shown that the two benzene rings are non planar with an angle of 55 1°. Owing to the non planar configuration, the dyes derived from DABSA possess a lower substantivity on fiber but better permeability in substrate, the color of these azo dyes could be matched by two individual azo dyes locating on both sides of the DABSA molecule.

关 键 词:Diaminobenzene sulfonanilide Configuration X  ray diffraction Non  carcinogenic substituent for benzidine Substantivity of dye Azo  hydrazone tautomers 

分 类 号:O62[理学—有机化学]

 

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