Syntheses Characterization of Chloro-cyclopentadienyltricarbonyl-molybdenum with β-Cyclodextrin Supramolecular  

作　　者：ZHANG YouMing 

出　　处：《Chemical Research in Chinese Universities》2001年第z1期32-33,共2页高等学校化学研究（英文版）

摘　　要：Organotransition metal complex have been extensively used as homogeneous catalysts in organic reactions and much effort has been paid to improve their activity and selectively. Cyclodextrins have been studied as a model of enzyme for selective catalysis. However, so far there are only a few reports on the inclusion compounds of organometallic complexes with cyclodextrins. Breslow et al.repored high acylation rates for β-CD using ferrocene derivatives and assumed β-CD substrate complexes as intermediate [1]..larad et al reported the preparation and propertics of cyclodextrin-ferrocen inclusion compounds as the first example of cyclodextrin inclusion compounds of organotransition metal complexes[2]. Song Le-Xin et al reported the supramolecular inclusion compound of β-cyclodextrin with cyclopentadieny-tricarbonylmanganese [3] .To our knowledge, there are no reports of inclusion compounds of β-CD with molybdenum organometallic complexes. In the present work we described the preparation and properties of the supramolecular of CpMo(CO)3Cl with β-CD in details.　　……

分 类 号：O6[理学—化学]