LAMINATION OF POLYMER FILMS BY BULK SURFACE PHOTOGRAFTING PROCESS AND PROPERTIES  

作　　者：B.Rnby 杨万泰 O.N.Tretinnikov V.Tokarev 

机构地区：[1]Department of Polymer Technology,Royal Institute of Technology, SE-100 44 Stockholm, Sweden [2]Department of Polymer Technology,Royal Institute of Technology, SE-100 44 Stockholm, Sweden Department of Polymer Science,Beijing University of Chemical Technology,Beijing 100029,China

出　　处：《Chinese Journal of Polymer Science》2001年第2期123-127,共5页高分子科学（英文版）

摘　　要：A new process for lamination of polymer films by 'bulk surface photografting' has been developed. The chemical component of the invention is that the curing of reactive solution between two substrates is initiated by the surface free radicals produced by aromatic ketones and surface-hydrogen of substrates. Using the new approach, two or more polymer films are bonded together by a grafted polymer network which is grafted to adjacent substrate surfaces. The technique has been applied to film substrates of different polymers such as polyolefins, polyesters, and polyamides which have abstractable hydrogens at the surface. The photolaminated film composites containing carrier films and an intermediate functional film of low permeability give strong laminates with high barrier properties, e.g, for oxygen and air.A new process for lamination of polymer films by 'bulk surface photografting' has been developed. The chemical component of the invention is that the curing of reactive solution between two substrates is initiated by the surface free radicals produced by aromatic ketones and surface-hydrogen of substrates. Using the new approach, two or more polymer films are bonded together by a grafted polymer network which is grafted to adjacent substrate surfaces. The technique has been applied to film substrates of different polymers such as polyolefins, polyesters, and polyamides which have abstractable hydrogens at the surface. The photolaminated film composites containing carrier films and an intermediate functional film of low permeability give strong laminates with high barrier properties, e.g, for oxygen and air.

关 键 词：PHOTOGRAFTING LAMINATION surface graft polymerization photolamination 

分 类 号：O484[理学—固体物理]