二元气体等温吸附-解吸中气分的变化规律  被引量:65

Variation Regularity of Gas ComponentConcentration in Binary-Component GasAdsorption-Desorption Isotherm Experiments

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作  者:唐书恒[1] 汤达祯[1] 杨起[1] 

机构地区:[1]中国地质大学能源地质系,北京100083

出  处:《中国矿业大学学报》2004年第4期448-452,共5页Journal of China University of Mining & Technology

基  金:国家重点基础研究发展规划项目(2002CB211702);国家自然科学基金项目(40272069);高等学校博士学科点专项科研基金项目(20020491003)

摘  要:进行了CH4-CO2和CH4-N2二元混合气体的等温解吸实验,分析了二元气体在解吸过程中各组分浓度的变化规律.结果表明,在CH4-N2二元气体的解吸过程中,吸附相中CH4组分的相对浓度逐渐增加,N2组分的相对浓度逐渐减少.在CO2-CH4二元气体的解吸过程中,吸附相中CO2组分的相对浓度逐渐增加,CH4组分的相对浓度逐渐减少.实验结果还证实了CO2在与CH4的竞争吸附中占据优势,而N2在与CH4的竞争吸附中处于劣势.注入CO2比注入N2可以更有效地置换或驱替煤层甲烷,提高煤层甲烷的采收率.The isotherm desorption experiments of binary-component gas of CH_4-CO_2 and CH_4-N_2 were carried out. The variation and concentration of each component in the experiment were analyzed. The experiment results indicate that the relative concentration of CH_4 in absorbed phase increases gradually and that of N_2 decreases gradually in the isotherm desorption experiment of CH_4-N_2 binary-component gas; However, the relative concentration of CO_2 in absorbed phase increases gradually and that of CH_4 component decreases gradually in the isotherm desorption experiment of CO_2-CH_4 binary-component gas. the above results have confirmed that CO_2 occupies the predominant position while N_2 is in an inferior position in the competitive adsorption with CH_4. Therefore, CO_2-injection can replace or displace the coalbed methane and enhance methane recovery more effectively than N_2-injection.

关 键 词:二元气体 等温解吸 竞争吸附 煤层甲烷 采收率 

分 类 号:P618.11[天文地球—矿床学] TD712[天文地球—地质学]

 

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