硫酸铜催化合成丁酮乙二醇缩酮  

Catalytic Synthesis of Butanone Glycol Ketal by Copper Sulfate

作　　者：吕宝兰[1] 曾兰洁[1] 杨水金[1] 

机构地区：[1]湖北师范学院化学与环境工程学院,黄石435002

出　　处：《化工中间体》2011年第11期30-32,共3页

摘　　要：以硫酸铜为催化剂,以丁酮和乙二醇为原料催化合成了丁酮乙二醇缩酮。正交实验筛选出适宜反应条件为:丁酮=0.2mol,n(丁酮):n(乙二醇)=1.0:1.4,催化剂用量占反应物料总质量的3.1%,带水剂环己烷用量为10mL,反应时间为3.5h。在此反应条件下,丁酮乙二醇缩酮的收率可达71.55%。Butanone glycol ketal was prepared from butanone and ethylene glycol using copper sulfate as catalyst.The optimal reaction conditions were screened by orthogonal test method.The yield of butanone glycol ketal can reach 71.55% under the optimum reaction conditions that butanone is 0.2mol,molar ratio of butanone to glycol is1.0:1.4,the quantity of catalyst is equal to3.1 of the feed stocks,the carrying-water agent is 10mL,and the reaction time is3.5h.

关 键 词：丁酮乙二醇缩酮 硫酸铜 催化剂 正交试验 

分 类 号：TQ2[化学工程—有机化工]