2-呋喃甲醛肟的合成  

Synthesis of 2-Furaldehyde Oxime

作　　者：吴雪松[1] 周莹[1] 肖红波[1] 曹福祥[1] 刘满珍[2] 

机构地区：[1]中南林业科技大学,湖南长沙410004 [2]常德职业技术学院,湖南常德415005

出　　处：《精细化工中间体》2012年第2期20-22,共3页Fine Chemical Intermediates

基　　金：湖南省2010年度科技计划重点项目(K1001012-11)

摘　　要：以糠醛为原料,与盐酸羟胺反应制得2-呋喃甲醛肟,研究了反应的酸碱度(pH)、时间、温度、原料配比对反应收率的影响,并确定了优化条件:原料配比n(盐酸羟胺)∶n(糠醛)=1.3∶1,温度20℃左右,反应时间1 h。2-Furaldehyde oxime was synthesized using furfural and oxammonium hydrochloride as the starting materials.The effects of the pH value,the reaction time,the temperature and the ratio of the reagents were studied.The optimized reaction conditions were obtained as follows:molar ratio of oxammonium hydrochloride to furfural 1.3 to 1,the reaction temperature 20℃,the reaction time 1 h.The target product was resulted in overall yield of 43% with purity above 98.7%.

关 键 词：糠醛 盐酸羟胺 2-呋喃甲醛肟 

分 类 号：O69[理学—化学]