铁系固体超强酸催化合成环己酮乙二醇缩酮的研究  

Study on Catalytic Synthesis of Ethylene Glycol Cyclohexane Ketal by Ferric Solid Superacid

作　　者：杜彬[1] 胡礼文[1] 褚昌武[1] 罗志臣[1] 

机构地区：[1]扬州工业职业技术学院,江苏扬州225127

出　　处：《辽宁化工》2012年第11期1133-1135,共3页Liaoning Chemical Industry

摘　　要：以铁系固体超强酸为催化剂,环己烷为带水剂,由环己酮和乙二醇合成环己酮乙二醇缩酮。实验发现:自制铁系固体超强酸催化剂具有良好的活性和稳定性。获得较佳工艺条件:n(环己酮):n(乙二醇)=1:1.4,m(环己酮):m(催化剂)=32.8,v(环己酮):v(环己烷)=2.08:1,反应时间1 h,产物收率达86%以上。Cyclohexanone ethylene ketal was synthesized from cyclohexanone and ethylene by using ferric solid superacid as the catalyst and cyclohexane as the water-carrying agent.The experiment results show that the ferric solid superacid has high activity and good stability;optimal synthesis conditions are as follows:molar ratio of cyclohexanone to ethylene is 1:1.4,mass ratio of cyclohexanone to the catalyst is 32.8:1,volume ratio of cyclohexanone to cyclohexane is 2.08:1,and reaction time is 1h.Under above conditions,the yield of cyclohexanone ethylene ketal is over 86%.

关 键 词：铁系固体超强酸 环己酮 乙二醇 环己酮乙二醇缩酮 

分 类 号：TQ2[化学工程—有机化工]