组合催化剂WO3+RaneyNi上高效转化菊芋秸秆制乙二醇(英文)  

Catalytic conversion of Jerusalem artichoke stalk to ethylene glycol over a combined catalyst of WO_3 and Raney Ni

作　　者：周立坤[1,2] 庞纪峰[1] 王爱琴[1] 张涛[1] 

机构地区：[1]中国科学院大连化学物理研究所催化基础国家重点实验室,辽宁大连116023 [2]中国科学院大学,北京100049

出　　处：《催化学报》2013年第11期2041-2046,共6页

基　　金：supported by the National Basic Research Program of China (973 Program, 2009CB226102);the National Natural Science Founda-tion of China (21176235)~~

摘　　要：采用商业WO3和Raney Ni为组合催化剂,以菊芋秸秆为反应原料制备了乙二醇.菊芋秸秆中含纤维素51.6 wt%、半纤维素10.3 wt%、木质素17.2 wt%、灰分1.7 wt%和水溶性物质19.2 wt%.木质素对纤维素和半纤维素的转化影响较小,而水溶性物质的存在抑制了乙二醇的生成,因此由未经过预处理的菊芋秸秆得到的乙二醇收率只有29.9%.而经简单的热水预处理可除掉其中的大部分水溶物,因而乙二醇收率提高到37.6%.此外,组合催化剂在经过热水预处理的菊芋秸秆的转化中表现出了更好的循环使用性能.同时考察了反应温度和时间对菊芋秸秆转化的影响.Jerusalem artichoke stalk(JAS) was employed as the feedstock for the production of ethylene glycol (EG) with a combined catalyst comprising commercial WO3 and Raney Ni.The raw JAS contains 51.6 wt% cellulose,10.3 wt% hemicellulose,17.2 wt% lignin,1.7 wt% ash,and 19.2 wt% water-soluble substances.It was found that the lignin component in the JAS had little effect on the conversion of hemicellulose while the water-soluble substances caused a negative effect,which led to an EG yield of only 29.9%.After a simple hot water pretreatment,most of the water-soluble substances were removed,and the EG yield was increased to 37.6%.Moreover,the hot water pretreatment also led to an improvement in the durability of the catalyst.The effects of reaction temperature and reaction duration were also investigated.

关 键 词：木质纤维素 菊芋秸秆 三氧化钨 雷尼镍 乙二醇 

分 类 号：TQ223.162[化学工程—有机化工]