氨基脲桥联杯[4]芳烃衍生物的合成及性能研究  

Synthesis and properties of semicarbazide-bridged calix[4]arene derivative

作　　者：郑林禄[1] 杨发福[2] 刘朝晖[1] 

机构地区：[1]宁德师范学院化学系,福建宁德3521002 [2]福建师范大学化学与材料学院,福州350007

出　　处：《齐齐哈尔大学学报（自然科学版）》2013年第1期52-55,共4页Journal of Qiqihar University(Natural Science Edition)

基　　金：福建省教育厅科技项目(JB10189);"服务海西建设"项目(2011H209)

摘　　要：设计并合成了下沿含缩氨脲基和席夫碱基的新型桥联杯[4]芳烃衍生物,经1H NMR、MS和元素分析等表征确证其结构;测定了新型桥联杯[4]芳烃衍生物对金属阳离子和氨基酸分子的两相萃取性能,结果表明新型主体分子通过多官能团的协同作用具有较好的配位性能。A new bridged calix[4]arene derivative containing semicarbazone groups and Schiff-base groups was designed and synthesized and its structure was confirmed by 1H NMR,MS and element analysis.Their binding properties for metal ions and amino acid were investigated.Experimental results showed that it possessed good extraction capabilities for cations and amino acid based on multifunctional complexation.

关 键 词：杯[4]芳烃 氨基脲 桥联 配位性能 

分 类 号：N55[自然科学总论]