氢还原下铁钼催化剂的表面性质  

XPS STUDY OF SURFACE PROPERTIES OF IRON-MOLYBDENUM CATALYST IN HYDROGEN REDUCTION

作　　者：张惠良[1] 李宗昌[1] 赵雪英[2] 傅献彩 

机构地区：[1]南京大学化学系,南京210008 [2]南京化工学院皮化系,南京210000

出　　处：《Chinese Journal of Catalysis》1993年第2期93-99,共7页催化学报（英文）

基　　金：中国科学院科学基金;南京大学现代分析中心测试基金;大连化学物理研究所催化基础国家重点实验室测试基金

摘　　要：用XPS对H_2还原下的铁钼催化剂的表面性质进行了研究。实验表明:H_2还原使表面钼离子由Mo^(6+)还原为Mo^(5+)和Mo^(4+),并与Fe^(3+)作用氧化为Mo^(6+);Fe^(3+)则由于与Mo^(5+)和Mo^(4+)作用以及H_2还原而变为Fe^(2+),从而形成了一个没有O_2存在,仅有H_2作用下的Mars-Krevelen氧化还原循环过程。在催化剂表面上生成的FeMoO_4,其Mo^(6+)的3d3/2和3d5/2的结合能值比Fe_2(MoO_4)_3中的Mo^(6+)的3d能级结合能值低。Mo(或Mo和Fe)离子键合的O^(2-)与H_2作用生成的Mo(Fe)-OH,其Os结合能的测定值低于键合于Mo(Fe)离子中的O^(2-)的Os结合能值,并且该结合能峰由于-OH间的相互作用结合成的水的脱附而消失。此外.给出了还原过程中H_2与催化剂表面O^(2-)相互作用的反应图式。The surface properties of iron-molybdenum catalyst in H2 reduction have been studied with X-ray photoelectron spectroscopy. The results showed that Mo6 + ions on the sample surface were reduced to Mo5 + and Mo4 + , and then were oxidized to Mo6+ once more by the interaction with Fe3+ ions. Meanwhile, the Fe3 + ions, due to the interaction with Mo5+ and Mo4+ and also due to the reduction by H2, were reduced to Fe2+. Thence, it exhibited a picture of the cycle of Mars-Krevelen redox mechanism for Fe-Mo-O catalyst in the selective oxidation, in which the oxygen was absent and only the hydrogen existed. It was found that the binding energy(b.e.) of 3d3/2 and 3d5/2 of Mo6+ (235.1 and 232.0eV) of FeMoO4 existed on the catalyst surface were lower than those in Fe2(MoO4)3,. The O2- species bonded to the Mo (or Mo and Fe) species interacted with hydrogen to produce Mo(Fe)-OH on 1he surface, and their b.e. of Ols was 528.4eV, which was somewhat lower than that of O2-(530.0eV)in lattice. When the reduction was continued, due to the interaction of the hydro-xyl radicals of Mo(Fe)-OH, water was formed, and the peak of Ols of Mo(Fe)-OH disappeared when the water desorbed. In addition, the reaction pattern of the interaction between hydrogen and O2- on the catalyst surface was given.

关 键 词：铁钼催化剂 表面性质 氢 还原 

分 类 号：O643.36[理学—物理化学]