Thermodynamic study and syntheses of β-SiAlON ceramics  

作　　者：DONG PengLi WANG XiDong ZHANG Mei GUO Min LI WenChao 

机构地区：[1]Department of Physical Chemistry,University of Science and Technology Beijing,Beijing 100083,China [2]Chinese Society for Metals,Beijing 100711,China [3]College of Engineering,Peking University,Beijing 100871,China

出　　处：《Science China(Technological Sciences)》2009年第11期3122-3127,共6页中国科学（技术科学英文版）

基　　金：Supported by the National Natural Science Foundation of China (Grant Nos. 50425415, 50372004);the National Basic Research Program of China ("973" Program) (Grant No. 2007CB613608)

摘　　要：Based on the thermodynamic study of β-SiAlON and one section of Si-Al-O-N phase diagram for Si/Al=9 at 1773 K, the pure β-SiAlON (Si6-ZAlZOZN8-Z) ceramics with different Z values (viz. 1.4, 1.8, 2.2, 2.6, 3.0) were synthesized at different temperatures using the pressure-less technique. The relationship of the experimental-saturated Z value (the maximum Z value at a constant temperature) with temperature was then discussed. The experimental results indicated that there is a good linear relationship between Z value and temperature, which is Z=_10.76+0.0071T (R=0.9985). The β-SiAlON stability regions at different temperatures were exhibited in a sketch phase diagram of Si3N4-SiO2-Al2O3-AlN system. In addi- tion, the relationship between experimental-saturated Z value and the lattice parameters was also characterized, and the linear regression results a=7.604+0.02872Z and c=2.908+0.02496Z were obtained, respectively.Based on the thermodynamic study of β-SiAlON and one section of Si-Al-O-N phase diagram for Si/Al=9 at 1773 K, the pure β-SiAlON (Si6-Z Al Z O Z N8-Z ) ceramics with different Z values (viz. 1.4, 1.8, 2.2, 2.6, 3.0) were synthesized at different temperatures using the pressure-less technique. The relationship of the experimental-saturated Z value (the maximum Z value at a constant temperature) with temperature was then discussed. The experimental results indicated that there is a good linear relationship between Z value and temperature, which is Z= ?10.76+0.0071T (R=0.9985). The β-SiAlON stability regions at different temperatures were exhibited in a sketch phase diagram of Si3N4-SiO2-Al2O3-AlN system. In addition, the relationship between experimental-saturated Z value and the lattice parameters was also characterized, and the linear regression results a=7.604+0.02872Z and c=2.908+0.02496Z were obtained, respectively.

关 键 词：SIALON THERMODYNAMICS synthesis OXYNITRIDE 

分 类 号：TQ174.75[化学工程—陶瓷工业]