氯化铜在MCM-41中的组装及其在萘满氧化反应中的催化性能  

Assembly of CuCl2 in MCM-41 and Its Catalytic Properties in Tetralin Oxidation

作　　者：米国瑞[1] 白洁[1] 赵继全[1] 

机构地区：[1]河北工业大学化工学院,天津300130

出　　处：《石油学报（石油加工）》2012年第S1期122-126,共5页Acta Petrolei Sinica(Petroleum Processing Section)

基　　金：国家自然科学青年基金项目(20806020)资助

摘　　要：使用接枝法将介孔分子筛MCM-41官能团化,进而利用负载官能团与氯化铜的配位实现氯化铜在MCM-41上的组装,得到了2个新型多相化催化剂。采用FT-IR、UV-Vis、AAS、XRD以及N2吸附等方法对其进行了表征,考察了多相化催化剂对叔丁基过氧化氢氧化萘满生成1-四氢萘酮反应的催化性能。结果表明,多相化催化剂在首次使用中表现出较好的催化活性,但是循环使用情况较差。Mesoporous molecular sieve MCM-41 was functionalized by a multi-step grafting method.Then CuCl2 was assembled in MCM-41 through the coordination of CuCl2 with the supported functional groups,and two novel heterogenized CuCl2 catalysts were obtained.The resulting catalysts were characterized by FT-IR,UV-Vis,AAS,XRD and nitrogen adsorption,and then evaluated through tetralin oxidation with tert-butyl hydroperoxide as the oxidant.The heterogenized catalysts performed well at first but got worsened afterwards in the recycle runs.

关 键 词：氯化铜 萘满 MCM-41 1-四氢萘酮 多相化催化剂 

分 类 号：O614.3[理学—无机化学]